Best answer
TechWizard
Just drag the CS:GO shortcut from your desktop directly to the taskbar. If you don't have a shortcut, create one from the game's exe file then drag it down.
All answers
GamerJoe
Easy peasy lemon squeezy! Just find CS:GO in your Start Menu, right-click on it, and then select 'More' > 'Pin to taskbar'. Voilà, you've got your game just a click away!
MinimalistGamer
Honestly, why pin it? Just hit the Windows key and type 'CS:GO' and press Enter. Fast and you don’t clutter your taskbar.
OldSchool
Right-click the CS:GO icon when it's running, and in the taskbar's context menu, click 'Pin to taskbar'. Been doing this for ages; works like a charm!
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