How to Unsync a PS4 Controller
To unsync a PS4 controller, plug it into another device or reset it using the small button on the back near the L2 shoulder button. Use a paperclip to hold it for a few seconds!
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You can unsync your PS4 controller by going to Settings > Devices > Bluetooth Devices and deleting it from the list there.
Just press and hold the PS and Share buttons simultaneously until the light bar blinks, then turn off the PS4. Simple!
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